Product ID:45058557 BAR-OX 450 ALKYD GLOSS ENAMEL SIGNAL YELLOW
MSDS Date:02/18/1993
FSC:8010
NIIN:00N046026
MSDS Number: BTQDR

DEVOE COATINGS COMPANY

4000 DU PONT CIRCLE
LOUISVILLE, KY 40207
US

Emergency Phone: 800-424-9300

Info Phone: 502-897-9861

Cage: 1HK86

DEVOE COATINGS CO

7600 LOUISVILLE, KY 40207-4802 US

Telephone: 502-897-9861

Cage: 1HK86

USED IN CONFINED AREAS, WEAR NIOSH/MSHA APPROVED

RTECS: 99999999Z

RESPIRATOR WHEN FLAME CUTTING, WELDING, BRAZING &

RTECS: 99999999Z

SAFETY & HLTH STANDARDS IN THE MIXING, APPLIC &

RTECS: 99999999Z

AND DECOMP PRODUCTS DURING WELDING & FLAME CUTTING

RTECS: 99999999Z

LONG DISTANCES. PREVENT BUILD-UP BY REMOVING HEAVY

RTECS: 99999999Z

ELIMINATE ALL IGNITION SOURCES.

RTECS: 99999999Z

SAFETY EYEWEAR WITH SPLASH GUARDS OR SIDESHIELDS.

RTECS: 99999999Z

ALKYD RESIN

Fraction By Weight: 40%

CLAY(KAOLIN);(ALUMINUM SILICATE)

CAS: 1332-58-7

RTECS: GF1670500

Fraction By Weight: 5%

OSHA PEL 10 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

CRYSTALLINE SILICA (PC)

CAS: 7631-86-9

Fraction By Weight: <.1%

OSHA PEL 0.1 MG/M3 RDUST

ACGIH TLV: 0.1 MG/M3 RDUST

SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (HIGH FLASH

CAS: 64742-95-6

RTECS: WF3400000

Fraction By Weight: 5%

ACGIH TLV: 100 PPM(MFR)

5.

CAS: 64742-47-9

Fraction By Weight: 30%

PERM-YELLOW; (ORGANIC YELLOW)

CAS: 6358-31-2

Fraction By Weight: 10%

OSHA PEL 15 MG/M3 TDUST (MFR)

ACGIH TLV: 10 MG/M3 TDUST (MFR)

TITANIUM DIOXIDE. LD50 (ORAL,RAT) >24000 MG/KG.

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: <5%

OSHA PEL 10 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

6. LD50 (ORAL,RAT) >5 G/KG.

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <5%

OSHA PEL 100 PPM; 150 STEL

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

395.93 G/L.

RTECS: 9999999VO

Fraction By Weight: SEE ING

VOMITING. ASPIR OF VOMITUS CAN CAUSE CHEM

RTECS: 99999999Z

BY DELIBERATELY CONCENTRATING & INHALING THE

RTECS: 99999999Z

CLOSED CONTAINER UNTIL PROPERLY DISPOSED OF.

RTECS: 99999999Z

PRODUCT, THEN MIXTURE OF BASE & CONVERTER

RTECS: 99999999Z

ALL APPLICABLE PRECAUTIONS.

RTECS: 99999999Z

APPROVED CHEMICAL/MECHANICAL FILTER DESIGNED TO

RTECS: 99999999Z

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL: IRRIT OF RESP TRACT:
HDCH, NAUS, DIZZ, WEAKNESS & FATIGUE. EXTREME EXPOS CAN RSLT IN
UNCON & EVEN RESP ARREST. SKIN/EYE: CAUSES IRRIT. MAY BE HARMFUL IF
ABSORBED THRU SKIN. INGEST: CAN CA USE STOMACH &/INTESTINAL IRRIT,
NAUS, VOMIT & DIARRHEA. CHRONIC: REPORTS HAVE ASSOCIATED RPTD/PRLNG
(EFTS OF OVEREXP
Explanation of Carcinogenicity:CRYSTALLINE SILICA: IARC CLASS 2A (MFR).
(CAS NO. GIVEN BY MANUFACTURER IS FOR AMORPHOUS CRYSTALLINE SILICA
).
Effects of Overexposure:HLTH HAZ: OCCUPATIONAL OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. PRLGD/RPTD BREATHING
OF SPRAY MIST &/SANDING DUST OVER A PERIOD OF YEARS MAY CAUSE DUST
DISEASE OF THE LUN GS. CONTAINS CRYSTALLINE SILICA WHICH CAN CAUSE
LUNG DAMAGE & CANCER. RISK DEPENDS ON DURATION & LEVEL OF EXPOSURE.
Medical Cond Aggravated by Exposure:NONE, WHEN USED IN ACCORDANCE WITH
SAFE HANDLING AND USE INFORMATION.

First Aid:INHAL: IF EXPERIENCE DFCLTY BRTHG, LEAVE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DFCLTY IS EXPERIENCED, SUMMON MD ASSIST IMMED. IF
BRTHG CEASES, RESTORE USING APPROVED CPR TECHNIQUES & SUMMON MED
HELP IMMED. EYES: FLUSH IMMED W/LGE AMTS OF WATER FOR AT LEAST 15
MINS. GET MED ATTN. SKIN: WASH AFFECTED AREAS W/SOAP & WATER.
REMOVE SOILED CLTHG. GET MED ASSIST IF IRRIT PERSIST. DO NOT INDUCE
(ING 10)

Flash Point Method:SCC
Flash Point:100F,38C
Lower Limits:1%
Extinguishing Media:CO2, DRY CHEMICAL, FOAM OR OTHER NFPA APPROVED
METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZ PREF. IF
EXPOS TO FIRE/EXTREME HEAT, (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS & FLAME. DUE TO PRESSURE BUILD-UP, CLOSED
CNTNRS EXPOS TO EXTREME HEAT MAY EXPLODE.(SUPP DATA)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT(FLAMES,HOT SURFS,&
ELEC, STATIC/FRICTIONAL SPARKS). PVNT BRTHG OF VAPS. VENT AREA.
BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZ CAUTION INFO. CNTN SPILLED
MATL & REMOVE W/INERT ABSORB & NON-SPARKING TOOLS. STORE IN(ING
12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPARKS & FLAMES.
DO NOT SMOKE. PVNT BUILD-UP OF VAPS BY MAINTAINING CONTINUOUS FLOW
OF FRESH AIR. KEEP CNTNR CLSD WHEN NOT IN USE.
Other Precautions:DO NOT STORE ABOVE 120 DEGREES/NEAR FIRE/OPEN FLAME.
STORE LGE QTYS IN BUILDINGS TO COMPLY W/OSHA 1910.106. DO NOT
TRANSFER CONTENTS TO BOTTLES/OTHER UNLABELLED CNTNRS. DO NOT REUSE
EMPTY CNTNRS. IF M ATL IS PART OF TWO COMPONENT (ING 13)

Respiratory Protection:WHEN SPRAY APPLIED IN OUDOOR/OPEN AREAS & DURING
SANDING/GRINDING OPERATIONS USE NIOSH/MSHA APPRVD MECH FILTER RESP
TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY & SANDING. WHEN
USED IN RESTRICTED V ENT AREAS, WEAR NIOSH/MSHA (ING 15)
Ventilation:PROVIDE GENERAL DILUTION/LOCAL EXHAUST VENT IN VOL &
PATTERN TO KEEP AIR CONTAM CONC BELOW CURRENT APPLICABLE (ING 18)
Protective Gloves:SOLVENT IMPERMEABLE GLOVES.
Eye Protection:ANSI APPROVED SOLVENT RESISTANT (ING 22)
Other Protective Equipment:SOLVENT IMPERMEABLE CLOTHING & BOOTS TO
PREVENT SKIN CONTACT ARE RECOMMENDED.
Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE.
WASH HANDS BEFORE EATING/SMOKING.
Supplemental Safety and Health
FIRE FIGHT PROC: WATER SHOULD BE USED TO COOL CLSD CNTNRS & PVNT PRESS
BUILD UP/POSS AUTO-IGNIT. EXPLO HAZ: NEVER USE WELDING/CUTTING
TORCH ON/NEAR CNTNR(EVEN EMPTY) AS PROD OR RESIDUE MAY IGNITE. DUR
ING EMERG CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS
MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN.

HCC:F4
Boiling Pt:B.P. Text:>279F,>137C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:50.36

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY CAUSE TOXIC FUMES WHEN HEATED TO
DECOMPOSITION. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.